Product ID:N4761 LT GREEN TREE MARKING PAINT
MSDS Date:04/07/1992
FSC:8010
NIIN:01-273-3769
MSDS Number: BNTRY

NILES CHEMICAL PAINT CO

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MICHAEL LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

MINERAL SPIRITS (VAPOR PRESSURE 2.0 MM HG @ 20C)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 47%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 18%

PM ACETATE (VAPOR PRESSURE 3.7 MM @ 20 C)

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 12%

COBALT COMPOUNDS (AS CO) (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE (AS MN) (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

BUTYL CELLOSOLVE (VAPOR PRESSURE 0.6 MM HG @ 20C)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: <1%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

PROPRIETARY INGREDIENTS

Fraction By Weight: BALANCE

4.46 LBS/GAL.

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION, LACRIMATION,
REDNESS, BLURRED VISION, VISUAL DISTURBANCES AND EYE BURNS. SKIN:
HARMFUL IF ABSORBED THRU SKIN. CAN BE ABSORBED IN TOXIC AMOUNTS
ESPECIALLY FROM PROLONGED/REPEAT ED EXPOSURES. BREATHING: NASAL &
RESP IRRITATION, CNS DEPRESSION (DIZZINESS, DROWSINESS, WEAKNESS,
FATIGUE, CONFUSION)
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA.
Effects of Overexposure:NAUSEA, HEADACHE, VERTIGO, POSSIBLE
UNCONSCIOUSNESS, EVEN ASPHYXIATION. SWALLOWING: GASTROINTESTINAL
IRRITATION, ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA, BLINDNESS
AND EVEN DEATH. CHRONIC EFFECTS: HEMOLYSIS, HEMOGLOBINURIA. TARGET
ORGANS: SKIN, EYES, RESP SYS, CNS, GI TRACT, LIVER, KIDNEYS,
LYMPHOID SYSTEM, BLOOD.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHAL: MOVE TO FRESH AIR IMMED. IF BREATHING STOPPED, GIVE
ARTIF RESPIRATION. GET MED AID ASAP. SKIN: WASH W/SOAP & WATER.
EYE: IMMED FLUSH W/WATER 15 MIN, OCCAS LIFT EYELIDS. GET MED AID
IMMED. DON'T WEAR CONTACT LENSES WHEN WORKING W/MAT'L. SWALLOW:
INDUCE VOMIT IMMED BY DRINKING 2 GLASSES WATER & STICK FINGER DOWN
THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MED
AID IMMED.

Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:0.8
Upper Limits:36.0
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN POS
PRESS MODE & FULL PROTECT CLOTH. MAY USE WTR TO COOL CLSD CNTNR
(PREVENT PRESS BLDUP/AUTOIGNIT/EXPLOS)EXPOSED TO HEAT
Unusual Fire/Explosion Hazard:KEEP CNTNRS CLSD. ISOLATE FROM HEAT,
IGNIT SOURCE. CLSD CNTNRS MAY EXPLODE W/HEAT. APPLIC TO HOT SRFCS
REQ SPCL PRECAUTION. OVEREXPOS TO DECOMP PROD-HEALTH HZD.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. MINIMIZE
BREATHING OF VAPORS & AVOID SKIN CONTACT. ABSORB WITH AN INERT
MATERIAL SUCH AS CLAY, SOIL OR COMMERCIALLY AVAILABLE ABSORBENT.
SHOVEL RECLAIMED LIQUID & ABSOR BENT INTO RECOVERY OR SALVAGE DRUMS
FORDISPOSAL.

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.

Respiratory Protection:WEAR APPROPRIATE (TC-23C-75) FITTED HALF-MASK OR
FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER APPLIC UNLESS
AIR MONITORING DEMONSTRATES VAPOR/MIST LEVELS ARE BELOW TLV. FOLLOW
RESPIRATOR MFR' S DIRECTIONS FOR USE.
Ventilation:PROVIDE SUFF VENT (VOL/PATTRN) TO KEEP AIR CONC BELOW PEL/
TLV. REMOVE DECOMP PROD. VENT VAPOR EMIT WHEN BAKING FINISHES
Protective Gloves:NITRILE OR VITON GLOVES.
Eye Protection:CHEM GOGGLES,SFTY GLASSES,FACE SHIELDS
Other Protective Equipment:NITRILE, VITON GLOVES & CLOTHING AS NEEDED
TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH PROMPTLY WHEN SKIN BECOMES CONTAM. REMOVE
CLOTHING THAT BECOMES WET (FLAMMABILITY HAZARD), WASH BEFORE REUSE.
Supplemental Safety and Health
IF POTENTIAL FOR CONTACT. WASH HANDS BEFORE EATING, SMOKING OR USING
RESTROOM.

HCC:F4
Boiling Pt:B.P. Text:146 TO 330F
Vapor Density:> AIR
Spec Gravity:1.083
Viscosity:40-45SZ#2
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Percent Volatiles by Volume:69.26
Corrosion Rate:MINIMAL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, CAUSTICS.
Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPPING.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS. D001, IGNITABLE

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.